I remember were we talking about this the other day.
To linux users the root filesystem layout is what it is. They know where everything is and how its structured. Its how its been forever.
For new users it may help them understand where stuff is installed since they like to reference everything back to windows.
In terms of switching, like i said it may help new users but if you look at it from the other side, it might just be better for them to get used to the regular system because its basicly the standard for all distros. For example if a new user starting using Gobolinux then decides to try another distro, they might be lost.
Either way, package management is the key and Gobolinux's way doesn't sound very good. Dependency management is very important.