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Linux: ~/.tremulous/base/Mac: ~/Library/Application\ Support/Tremulous/base/Windows: C:\Documents and Settings\username\Local Settings\Application Data\Tremulous\base\
Nothing can be made idiot-prove ...
Is Xire mainly you to see how many hours of your life you waste playing video games?
I'm pretty sure that all you have to do is rename your tremulous.exe to quake3.exe then repoint xfire to it.